SUBSCRIBESUBSCRIBESUBSCRIBEHomeHistory & SocietyScience & TechBiographiesAnimals & NatureGeography & TravelArts & CultureProConMoneyGames & QuizzesVideosOn This DayOne Good FactDictionaryNew ArticlesHistory & SocietyLifestyles & Social IssuesPhilosophy & ReligionPolitics, Law & GovernmentWorld HistoryScience & TechHealth & MedicineScienceTechnologyBiographiesBrowse BiographiesAnimals & NatureBirds, Reptiles & Other VertebratesEnvironmentFossils & Geologic TimeInsects & Other InvertebratesMammalsPlantsGeography & TravelGeography & TravelArts & CultureEntertainment & Pop CultureLiteratureSports & RecreationVisual ArtsImage GalleriesPodcastsSummariesTop QuestionsLists and StoriesBritannica KidsAsk the ChatbotGames & QuizzesHistory & SocietyScience & TechBiographiesAnimals & NatureGeography & TravelArts & CultureProConMoneyVideoschemical bondingIntroductionHistorical reviewEmergence of quantitative chemistryThe law of conservation of massThe law of definite proportionsThe law of multiple proportionsDaltonâs atomic theoryFeatures of bondingValenceIonic and covalent compoundsThe periodic tableAdditional evidence of atomsAvogadroâs lawKinetic theory of gasesVisual images of atomsMolecular structureInternal structure of atomsDiscovery of the electronContributions of LewisAtomic structure and bondingAtomic structureThe Bohr modelThe quantum mechanical modelThe location of the electronQuantum numbersShapes of atomic orbitalsThe building-up principleHydrogen and heliumLithium through neonSodium through argonPotassium through kryptonPeriodic arrangement and trendsArrangement of the elementsPeriodic trends in propertiesAtomic sizeIonization energyElectron affinityElectronegativityBonds between atomsThe formation of ionic bondsLewis formulation of an ionic bondThe Born-Haber cycleFactors favouring ionic bondingCovalent bondsLewis formulation of a covalent bondAdvanced aspects of Lewis structuresMultiple bondsResonanceHypervalenceIncomplete-octet compoundsElectron-deficient compoundsMolecular shapes and VSEPR theoryApplying VSEPR theory to simple moleculesMolecules with multiple bondsMolecules with no central atomLimitations of the VSEPR modelThe polarity of moleculesThe quantum mechanics of bondingValence bond theoryFormation of Ï and Ï bondsPromotion of electronsHybridizationResonant structuresMolecular orbital theoryMolecular orbitals of H2 and He2Molecular orbitals of period-2 diatomic moleculesMolecular orbitals of polyatomic speciesThe role of delocalizationComparison of the VB and MO theoriesIntermolecular forcesRepulsive forceDipoleâdipole interactionDipoleâinduced-dipole interactionDispersion interactionThe hydrogen bondVarieties of solidsIonic solidsMolecular solidsNetwork solidsMetalsAdvanced aspects of chemical bondingTheories of bonding in complexesCrystal field theoryLigand field theoryCompounds displaying unique bondingOrganometallic compoundsBoranesMetal cluster compoundsComputational approaches to molecular structureReferences & Edit HistoryRelated TopicsImages & Videosbonding summaryFacts You Should Know: The Periodic Table QuizIns and Outs of ChemistryWhat are the basics of chemical reactions?What happens to chemical bonds when a chemical reaction takes place?How are chemical reactions classified?ScienceChemistrychemical bondingFacebookXhttps://www.britannica.com/science/chemical-bondingACS Publications - A Review of Research on the Teaching and Learning of Chemical BondingBiology LibreTexts - Chemical BondingNational Center for Biotechnology Information - PubMed Central - Chemical Bonding: The Journey from Miniature Hooks to Density Functional TheoryNature - Nature Communications - The role of references and the elusive nature of the chemical bondCORE - Challenges to the Structural Conception of BondingThe University of Hawaiʻi Pressbooks - Chemical BondsOpenStax - Organic Chemistry - Development of Chemical Bonding TheoryKwantlen Polytechnic University - Chemical BondingCCCS Open Textbooks - Anatomy and Physiology - Chemical Bonding and MoleculesThe University of Sydney - Chemical Bonding (PDF)Brigham Young University - Chemical BondsNational Center for Biotechnology Information - PubMed Central - A Critical Look at Linus PaulingÃâs Influence on the Understanding of Chemical BondingProjects at Harvard - Atomic Structure & Chemical BondingPeter W. Atkins
Fellow of Lincoln College, University of Oxford; Lecturer in Physical Chemistry, University of Oxford. Coauthor of Molecular Quantum Mechanics and many others; author of On Being and...Britannica Editors
Encyclopaedia Britannica's editors oversee subject areas in which they have extensive knowledge, whether from years of experience gained by working on that content or via study for an advanced degree....HistoryintermoleculargasesliquidsenergygascompoundssolidsJohannes van der Waalsvan der Waals forcesargonatomhydrogen chlorideintermolecular potential energyforcepotential energymanifestationwavePauli exclusion principleelectronsspinheliummoleculeelectric dipoleatomscondensationhydrogen chlorideliquidtemperaturesweak interactionpolarizationacquireschargeDispersionbenzenehydrocarbonsbrominesolidelementsphosphorussulfurelectrontransient
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